A Molecular Picture of Biofuel Decomposition: Pyrolysis of Furan and Select Furanics
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منابع مشابه
Biobased Furanics: Kinetic Studies on the Acid Catalyzed Decomposition of 2-Hydroxyacetyl Furan in Water Using Brönsted Acid Catalysts
Biobased furanics like 5-hydroxymethylfurfural (5-HMF) are interesting platform chemicals for the synthesis of biofuel additives and polymer precursors. 5-HMF is typically prepared from C6 ketoses like fructose, psicose, sorbose and tagatose. A known byproduct is 2-hydroxyacetylfuran (2-HAF), particularly when using sorbose and psicose as the reactants. We here report an experimental and kineti...
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Due to the rapidly growing interest in the use of biomass derived furanic compounds as potential platform chemicals and fossil fuel replacements, there is a simultaneous need to understand the pyrolysis and combustion properties of such molecules. To this end, the potential energy surfaces for the pyrolysis relevant reactions of the biofuel candidate 2-methylfuran have been characterized using ...
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The increase in the population of the planet and the rapid economic growth and, consequently, the high consumption of energy has created many environmental problems in the globe. Due to these reasons and the lack of renewability of these fossil fuels, there has been a steep trend towards the production of renewable fuels from natural sources, one of which is the production of energy from biomas...
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Pyrolysis-gas chromatography-mass spectrometry (MS) was used to identify the major organic products produced by pyrolysis of three foundry sand resins: (i) Novolac and (ii) phenolic urethane (PU) (both phenol-formaldehyde based resins) and (iii) furan (furfuryl alcohol based resin). These resins are used in the metal casting industry as a "sand binder" for making cores (used to produce cavities...
متن کاملPyrolysis of furan in a microreactor.
A silicon carbide microtubular reactor has been used to measure branching ratios in the thermal decomposition of furan, C4H4O. The pyrolysis experiments are carried out by passing a dilute mixture of furan (approximately 0.01%) entrained in a stream of helium through the heated reactor. The SiC reactor (0.66 mm i.d., 2 mm o.d., 2.5 cm long) operates with continuous flow. Experiments were perfor...
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تاریخ انتشار 2015